Linear Formula SbCl 3. US DOT UN1733, Antimony Trichloride, Solid, 8, pg II TDG UN1733, ANTIMOY TRICHLORIDE, SOLID, 8, pg II IMDG UN1733, ANTIMOY TRICHLORIDE, SOLID, 8, pg II Marine Pollutant No IATA/ICAO UN1733, Antimony Trichloride, Solid, 8, pg II 15. During combustion at a temperature higher than 6000°F, the halogen produces hydrochloric or hydrobromic acid that reacts with the BrightSun antimony oxide. View information & documentation regarding Antimony(III) chloride, including CAS, MSDS & more. PubChem Substance ID ⦠... Antimony trichloride The information presented above is offered for informational purposes only. Duquesne, PA 15110 . SbCl3 is Cementite structured and crystallizes in the orthorhombic Pnma space group. Oxides of antimony. [9], SbCl3 is only a weak Lewis base,[7] however some complexes are known for example the carbonyl complexes, Fe(CO)3(SbCl3)2 and Ni(CO)3SbCl3. ... Antimony trichloride is listed in the TSCA inventory and in SARA 313 (as antimony compounds). Antimony (atomic symbol: Sb, atomic number: 51) is a Block P, Group 15, Period 5 element with an atomic radius of 121.760. It is a white powder insoluble in water, alcohol and ⦠[9], In the gas phase SbCl3 is pyramidal with a Cl-Sb-Cl angle of 97.2° and a bond length of 233 pm. Chemical Intermediates - Antimony oxide is used as a chemical intermediate for the production of a wide variety of other antimony compounds, i.e. It is corrosive to tissue. See ANTIMONY COMPOUNDS and ANTIMONY(III) CHLORIDE.When heated to decomposition it emits very toxic fumes of Cl â and Sb. - Hydrogen fluoride, Antimony oxide. These eight atoms can be considered as forming a bicapped trigonal prism. Decomposition Products: Arsenic oxides, hydrogen chloride Conditions to Avoid: Moisture. Antimony trichloride is the chemical compound with the formula SbCl3. Antimonyl chloride, SbOC1, is produced by the decomposition of one part of the trichloride with four parts of water. Hazard Codes T, N, C Risk Statements 34-51/53-40-23/24/25-14 After oral administration of high doses of antimony trichloride to mice (up to 1.5 g/kg body weight), the replicative DNA synthesis and the repair of DNA strand breaks after treatment with -rays were delayed (Ashry et al. [10] In SbCl3 each Sb has three Cl atoms at 234 pm showing the persistence of the molecular SbCl3 unit, however there are a further five neighboring Cl atoms, two at 346 pm, one at 361 pm, and two at 374 pm. In episode 12 of the third season of the popular British program All Creatures Great and Small (adapted from chapter six of the book All Things Wise and Wonderful), several calves died following an episode of nonspecific gastroenteritis, the cause of which was later determined to be ingestion of antimony trichloride present in a solution used to dissolve their horn stubs. ... A colorless, solid compound, toxic and corrosive. C, preferably 80.degree. It has been used in the past to dissolve and remove horn stubs from calves without having to cut them off. This results in the formation of one of these compounds: antimony trichloride, antimony oxychloride, antimony tribromide or antimony oxybromide. ANTIMONY . MDL number MFCD00011212. The point to note here is that the all eight close neighbours of Bi are closer than the eight closest neighbours of Sb, demonstrating the tendency for Bi to adopt higher coordination numbers.[10][7]. Prepared in this way it contains a small quantity of the unaltered chloride, which can be removed by ether or carbon bisulphide. sodium antimonate, potassium antimonate, antimony pentoxide, antimony trichloride, tartar emetic, antimony sulfide. It is a white powder insoluble in water, alcohol and ether. It is shipped as a solid or liquid solution. The poison gas stibine is formed by the action of acidic reducing agents on antimony compounds. Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally. (HSDB, 1997) Major products of combustion When heated to decomposition antimony trichloride emits fumes of chloride and antimony. Fumes at room temperature. Antimony trichloride is prepared by reaction of chlorine with antimony, antimony tribromide, antimony trioxide, or antimony trisulfide. antimony trioxide acrylonitrile Prior art date 1973-08-24 Legal status (The legal status is an assumption and is not a legal conclusion. This material contains Antimony trichloride (listed as Antimony), 99+%, (CAS# 10025-91-9) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373. C. The distillation is preferably conducted under a pressure of between 20 and 130 mmHg. Thermal decomposition study of antimony (III) tribromide and aromatic amine adducts. of chloro- form (u.s.P. The chloroform contained 1 per cent alcohol. Pure SbF3 is then obtained by carefully evaporating all of the water from the crude product, which is ⦠SAFETY DATA SHEET . In case of dust formation, take appropriate measures ⦠Antimony trichloride was washed several times with chloroform and dried in a desiccator. Expired - Lifetime Application number US05/473,582 Inventor Shoichiro Takezoe ⦠Sb3+ is bonded in a distorted T-shaped geometry to three Cl1- atoms. The âHazard classification and labellingâ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Provided is a method for producing a crystalline antimony pentoxide hydrate which can be produced and ⦠SbCl3 is a reagent for detecting vitamin A and related carotenoids in the Carr-Price test. The antimony trichloride reacts with the carotenoid to form a blue complex that can be measured by colorimetry. "Phase transitions mechanism and distortion of SbCl, "Antimony: Inorganic Chemistry" R. Bruce King, National Institute for Occupational Safety and Health, https://en.wikipedia.org/w/index.php?title=Antimony_trichloride&oldid=981122764, Chemical articles with multiple compound IDs, Multiple chemicals in an infobox that need indexing, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Creative Commons Attribution-ShareAlike License, This page was last edited on 30 September 2020, at 12:16. Phosphorus trioxide is the chemical compound with the molecular formula P 4 O 6.Although the molecular formula suggests the name tetraphosphorus hexoxide, the name phosphorus trioxide preceded the knowledge of the compound's molecular structure, and its usage continues today. Prepared in this way it contains a small quantity of the unaltered chloride, which can be removed by ether or carbon bisulphide. It has a very potential use as a Lewis acid catalyst in synthetic organic transformation. a: the trichloride SbCl 3 obtained as a colorless hygroscopic caustic crystalline solid from antimony and chlorine and used chiefly in coloring metals (such as iron, zinc), as a catalyst, and as a mordant â called also butter of antimony High temperatures. ... Picoline as ligand with antimony trichloride and triiodide. With a limited amount of water it forms antimony oxychloride releasing hydrogen chloride: With more water it forms Sb4O5Cl2 which on heating to 460° under argon converts to Sb8O11Cl12. Belongs to the Following ⦠SbCl3 is readily hydrolysed and samples of SbCl3 must be protected from moisture. Antimony trichloride is the chemical compound with the formula SbCl3. It is suggested in that SbCIa is formed due to a three stage endothermic decomposition of antimony oxychloride, formed during the reaction of antimony oxide with hydrogen chloride evolved during the decomposition of the organic chloro-compound. J Therm Anal Calorim. The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony. [7], SbCl3 readily forms complexes with halides, but the stoichiometries are not a good guide to the composition,[7] for example the (C5H5NH)SbCl4 contains a chain anion with distorted SbIII octahedra. Product Name: Antimony . The structure is zero-dimensional and consists of four antimony trichloride molecules. The number of electrons in each of antimony's shells is 2, 8, 18, 18, 5 and its electron configuration is [Kr] ⦠(57) [Summary] [Purpose] High-purity antimony pentoxide hydrate, which has a high cation exchange capacity and a low residual anion impurity concentration, and is useful for inorganic ion exchangers and as a resin filler. Antimony(III) chloride, Butter of antimony, Antimonous chloride, Stibous chloride, Trichlorostibine, Except where otherwise noted, data are given for materials in their, Zarychta, B.; Zaleski, J. Hazardous decomposition products formed under fire conditions. [8], With nitrogen donor ligands, L, complexes with a stereochemically active lone-pair are formed, for example Ψ-trigonal bipyramidal LSbCl3 and Ψ-octahedral L2SbCl3. For more information call: 412-469-8466 (Monday - Friday 9:00 - 5:00 â¦
LçËÛú¾Y×KðZê¸[2]©h¦*÷x¶îH ó3ê)]Û(K]ØcÊÏ9W¥®TÞg((}¡³Ü©Ê^Á¤×z®ö©ôBÆÒb=`ñ_Õ\SÁø.ÑSÿ¿=FKddÐø´ ¨. The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony.Antimony trichloride is prepared by reaction of [11] When heated to decomposition, it emits very toxic fumes of fluoride and metallic antimony [Lewis, 3rd ed., 1993, p. 83]. Poison by ingestion. ), allowing it to stand, and decant,ing the clear liquid. In order to prevent the decomposition of antimony pentachloride into antimony trichloride and chlorine, it is advantageous to conduct the distillation of antimony pentachloride in a chlorine ⦠Investigations on the mechanism of the genotoxicity of antimony trichloride in cultured human ⦠REGULATORY INFORMATION TSCA Inventory Status All ingredients are listed on ⦠A solution of antimony trichloride in liquid hydrogen sulfide is a good conductor, though the applications of such are limited by the very low temperature or high pressure required for hydrogen sulfide to be liquid.[12]. The decomposition products, water and char, cool the flame reactions while slowing the production and volatilization of flammable decomposition products. Antimony trichloride has also been used as an adulterant to enhance the louche effect in absinthe. Corrosive. Antimony Trichloride (10025-91-9), >99% Section 4: First Aid Measures Always seek professional medical attention after first aid measures are provided. The CLP Regulation makes ⦠Sigma-Aldrich offers a number of Antimony(III) chloride products. Company: Angstrom Sciences, Inc. 40 South Linden Street . Antimony trifluoride is a white to gray crystalline solid, which is sometimes shipped as an aqueous solution. 1988). Antimony(III) chloride ReagentPlus ®, 99% Synonym: Antimony trichloride CAS Number 10025-91-9. The soft colorless solid with a pungent odor was known to the alchemists as butter of antimony. ... Antimony(III) fluoride may be prepared by treating antimony trioxide or trichloride with hydrofluoric acid. Antimony trichloride Revision Date 23-January-2018 Email: EMSDS.RA@thermofisher.com Creation Date 09-April-2010 Revision Date 23-January-2018 Print Date 23-January-2018 Revision Summary This document has been updated to comply with the requirements of WHMIS 2015 to align This ⦠Mutation data reported. Antimony chloride definition is - either of two chlorides of antimony:. OSHA SDS #: 25170 rev 101 3/27/2015 ANTIMONY TRICHLORIDE TS Page 4. These distances can be contrasted with BiCl3 which has three near neighbors at 250 pm, with two at 324 pm, and three at a mean of 336 pm. 10025-91-9: Density: 3,14 g/cm3 Solubility: H2O: soluble in water Similarly the salt (C4H9NH3)2SbCl5 contains a polymeric anion of composition [SbCl52−]n with distorted octahedral SbIII. Antimony Pentoxide The second most widely used antimony synergist is antimony pentoxide [1313-60-9] , Sb 2 O 5 , produced by the oxidation of the trioxide using either a ⦠(SAX's, 1996) Explosive limits NA Flammability Non flammable (OHM/TADS, 1997) Boiling point 283°C (DOSE, 1992) Density 3.14 at 20°C/4°C (MERCK, 1996) Vapour pressure 133.322 at ⦠to 130.degree. CAS Number: 7440-36-0 / EC Number: 231-146-5 . Molecular Weight 228.12 . It also may be made by treating antimony trioxide with concentrated hydrochloric acid. It is also used as a catalyst for polymerization, hydrocracking, and chlorination reactions; as a mordant; and in the production of other antimony salts. Clean Air Act: CAS# 10025-91-9 (listed as Antimony compounds) is listed as a hazardou s air pollutant (HAP). 3.43 mol antimony trichloride A 49.3 sample of CaCO3 was treated with aqueous H2SO4, producing calcium sulfate, 3.65 g of water and CO2(g). Antimony trichloride is the chemical compound with the formula SbCl3. to 100 cc. ANTIMONY TRICHLORIDE 99% AR/ACS Safety Data Sheet www.lobachemie.com 22/03/2019 7/10 Transport document description (IMDG) : UN 1733 ANTIMONY TRICHLORIDE, 8, II, MARINE POLLUTANT/ENVIRONMENTALLY HAZARDOUS Transport document description (IATA) : UN 1733 Antimony trichloride, 8, II, ⦠According to the unbalanced equation below, how many moles of antimony trichloride are formed when 4.00 mol of antimony is reacted with 5.14 mol of chlorine? Antimony trichloride is a colorless crystalline solid. adducts. Antimony oxychloride is soluble in ⦠Hazard classification & labelling Hazard classification and labelling. There ⦠DATE OF LAST REVISION: 0 6/12/15. EC Number 233-047-2. Exposure to air. Section 1: Identification . Antimony trichloride (âButter of Antimonyâ), ... SbOCl, is produced by the decomposition of one part of the trichloride with four parts of water. Its solution is used as an analytical reagent for chloral, aromatics, and vitamin A. - Workplace exposure limit value: 0.5 mg/m^3 respirable fraction for antimony and antimony compounds - Personal protective equipment: Respiratory protection: If workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. A saturated solution of this product was made by adding 30 gm. Decomposition Products: Thermal decomposition produces toxic vapors of hydrogen chloride, chlorine, phosgene. It is decomposed slowly by water to hydrochloric acid and antimony oxychloride. Name: Antimony trichloride: EINECS: 233-047-2 CAS No. ÃùuûÐoS)D¡ rF¤ ÉT=ú1\Ó There are one shorter (2.37 Å) and two longer (2.41 Å) SbâCl bond lengths. Control Parameters: 10025-91-9, Antimony Trichloride, ACGIH TLV: 0.5mg/m3, OSHA PEL: 0.5mg/m3 Appropriate Engineering controls: Emergency eye wash fountains and safety showers should be available in the immediate vicinity of use/handling.Provide exhaust ventilation or other engineering controls to keep the ⦠Shelf life: Poor, very hygroscopic. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) When heated to decomposition, emits toxic fumes of Cl and Sb. Reagent for detecting vitamin a and related carotenoids in the past to dissolve and remove horn stubs from without! Pollutant ( HAP ) polymeric anion of composition [ SbCl52− ] n with octahedral... Toxic fumes of Cl â and Sb decomposition it emits very toxic of! 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Is offered for informational purposes only US05/473,582 Inventor Shoichiro Takezoe ⦠antimony trichloride molecules antimony trioxide, antimony... Or trichloride with hydrofluoric acid in a distorted T-shaped geometry to three Cl1- atoms chloroform and dried in a T-shaped...